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These newer disciplines have given physical organic chemists fertile ground in which to study the interrelationships of structure and reactivity. New life has been breathed into the field because it has embraced newer chemical disciplines, such as bioorganic, organometallic, materials, and supramolecular chemistries. In our opinion, physical organic chemistry is alive and well in the early twenty-first century. Some would argue that the last century also saw the near death of the field. "The twentieth century saw the birth of physical organic chemistry - the study of the interrelationships between structure and reactivity in organic molecules - and the discipline matured to a brilliant and vibrant field.
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